Introduction: Well known for their pleasant smell, esters have a specific formula. The main Carbon is attached to an R group and two Oxygen molecules. One of these molecules is double bonded to the Carbon, while the other is single bonded, and has an R’ group attached on the other side. The structural formula is R–COO–R’. Esters are known for their ability to create a wide variety of smells and flavors, and are commonly used for this purpose. Examples if these odors can include apple, banana, grape, mint. Many foods can be flavored with an ester, and contain none of the actual ingredients of that taste. This is common in certain juices and candies. Esters are also commonly used in scented candles or air fresheners for cars to give a variety …show more content…
The ester studied was “3,” the acid used was 9.5 mL of “B,” and the alcohol used was 18.1 mL of “C.” A few substances were added to augment the production of the ester. Sulfuric acid (H2SO4) was added using a dropper bottle to catalyze the reaction. The desiccant in this reaction was drierite and was used to absorb the water byproduct. This prevented the ester from breaking apart into its constituents. The cold finger condenser was used to trap evaporated gas from the heated mixture, and condense it back into …show more content…
If the ratio was larger, or smaller, this would indicate that there is too much of one or the other. In this experiment, the goal was to form an ester and prevent the reverse reaction from occurring. An incorrect molar ratio could prevent the completion of this reaction, and impede this goal. Conclusion: In this lab, the production of esters and the process of esterification was studied. Concepts learned include molar ratio calculation, and ester constituents (carboxylate acid and alcohol). In addition, the use of a cold finger condenser and its purpose in ester reactions was discovered. The effects of drierite on reactions and its ability to absorb water was also studied. Concepts of stoichiometry were reviewed from previous classes, and integrated into this lab experiment as well. Citations: Thorne, E. J. (2015). Laboratory Manual for General Chemistry. Wiley Custom Learning Solutions. Print. Tro, N. J. (2015). Chemistry: Structure and Properties. Upper Saddle River, NJ: Pearson.
The contents of the reaction flask were slowly poured into the 250 ml Erlenmeyer flask which already contained 13.75 g ice and 25 ml of 10% H2SO2. The round bottom-flask was rinsed with 2.0 mL of 10% H2SO4 and 2.0 mL of diethyl ether, and the rinses were added to the mixture in an Erlenmeyer flask. Then, the mixture was swirled until all the salt was hydrolyzed, and the product distributed well into the ether layer. A
The other possibility for the unknown neutral, 1,4-dimehtoxybenzone, would have had an H NMR spectra with two peaks; however, the spectra obtained did not show chemical shifts for an aromatic ester group and had many hydrogens in the aromatic
Introduction: Enzymes are needed for survival in any living system and they control cellular reactions. Enzymes speed up chemical reactions by lowering the energy needed for molecules to begin reacting with each other. They do this by forming an enzyme-substrate complex that reduces energy that is required for a specific reaction to occur. Enzymes determine their functions by their shape and structure. Enzymes are made of amino acids, it 's made of anywhere from a hundred to a million amino acids, each they are bonded to other chemical bonds.
In addition, phenolphthalein was added as an indicator. The aliquots were titrated against sodium hydroxide (NaOH) solution until end point was reached, after which volume of NaOH consumed was recorded. The value of the rate constant, k, obtained was 0.0002 s-1. The experiment was then repeated with 40/60 V/V isopropanol/water mixture and a larger value of k = 0.0007 s-1 was obtained. We concluded that the rate of hydrolysis of (CH3)3CCl is directly proportional to water content in the solvent mixture.
The dehydration of 2-methylcyclohexanol takes place at the bottom of the Hickman still. As the Hickman still heats up within the sand bath, the products evaporate and travel higher up in the still where they condense into a liquid and fall within the collection ring, thus separating the product from the remaining water. Drierite (CaSO4) is also added as a drying agent to absorb any leftover water within the product. The purity of the product will then be analyzed with infrared spectroscopy, paying attention to OH peak if it is present. Chemical Reactions: Data and Observations: Material Volume Mol.
There are three main types of ester hydrolysis reactions: base-facilitated hydrolysis (saponification), acid-catalyzed hydrolysis (with the reverse reaction the Fischer Esterification), and enzymatic hydrolysis, triggered by lipases. Base-facilitated hydrolysis generally uses aqueous NaOH as a reagent, providing the base that attacks the carbonyl and begins the hydrolysis. Saponification hydrolyzes esters into carboxylic acids or fatty acids and alcohols. This has been used for thousands of years to produce soap from fatty acids as the salts produced from saponification can dissolve fats, surrounding them with micelles and allowing them to be easily removed with water1. It can also be used to produce glycerol from triglycerides.
Vacuum filtration was performed on the crude product, then it was recrystallized for purification. Melting point analysis was conducted on the recrystallized product to determine its identity. 3. The three possible mechanisms in this experiment were syn-addition
The purpose of this experiment is to perform a two step reductive amination using o-vanillin with p-toluidine to synthesize an imine derivative. In this experiment, 0.386 g of o-vanillin and 0.276 g of p-toluidine were mixed into an Erlenmeyer flask. The o-vanillin turned from a green powder to orange layer as it mixed with p-toludine, which was originally a white solid. Ethanol was added as a solvent for this reaction. Sodium borohydride was added in slow portion as the reducing agent, dissolving the precipitate into a yellowish lime solution.
The yellow solution containing the reactants was slowly poured into the beaker containing the cold water and the acid in order to cause the precipitation of the alcohol, 9-fluorenol and to destroy (hydrolyzed) the unreacted excess sodium borohydride. Subsequently, the white precipitate was vacuum filtered and washed twice with 20.0 ml portions of distilled cold water by pouring the liquid into the Buchner Funnel during filtration. It was necessary to wash the alcohol prior to recrystallization considering that the C-OH bond is easily broken by the formation of a stable and benzylic carbocation that favors the synthesis of difluorenyl ether. Finally, before the purification by recrystallization of the obtained product, the white solid alcohol was allowed to dry over a period of a
Experiment 2 Report Scaffold (Substitution Reactions, Purification, and Identification) Purpose/Introduction 1. A Sn2 reaction was conducted; this involved benzyl bromide, sodium hydroxide, an unknown compound and ethanol through reflux technique, mel-temp recordings, recrystallization, and analysis of TLC plates. 2. There was one unknown compound in the reaction that was later discovered after a series of techniques described above.
and esters. In the case of hydrolytic reaction, the steam produced during the processing of food containing water causes the hydrolysis of triglycerides, resulting in the formation of free fatty acid, glycerol, monoglycerides, and diglycerides. High free fatty acid level, i.e. quantum of free fatty acids greater than 1 mg/g KOH, results in generation of high amounts of undesirable soap simultaneously with transestrification reaction. In the alkali-catalyzed process, the presence of free fatty acid (greater than 1 mg/g KOH) and water in the oil can cause high amounts of undesirable soap formation, also consuming some quantity of alkaline catalyst and reduces the effectiveness, all of which result in a lower conversion. Therefore, for the feedstock with high free fatty acids, it is essential to have a pretreatment stage before subjecting it to transesterification process.[16] 1.2 Pretreatment Process for Waste Cooking Oil Pretreatment of waste cooking oil consists of physical treatment for removing the suspended solid contaminants and chemical treatment processes mainly for deacidification.
“Chemists created hundreds of new projects, from medicines such as aspirin to perfumes and soaps. Newly developed chemical fertilizers
Retrieved from http://goo.gl/T3k34H Employee Benefits. (2015). American Chemistry Council. Retrieved from http://goo.gl/3yf0Wu Materials Science. (2015). ACS Chemistry for Life.
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In addition, they also find applications in the preparation of wide variety of products such as drugs, rocket propellants, celluloid, photographic developers, paints and polishes, electric batteries, coloured glass, safety matches etc (Beard and Noe 1981; Dunlap 1982; Hirai 1999; Meidl 1970; Plunkett 1966; Windholz et al., 1976; Ware 1994) (Table